COMPOUND OF OXYGEN

 

COMPOUND OF OXYGEN

OXIDES

Oxides are binary compounds formed when elements combines with oxygen. Binary compounds are compounds containing two elements only.

CLASSIFICATION OF OXIDES

1.       ACIDIC OXIDES: These are oxides formed between a non-metal and oxygen e.g.

C + O2            CO2;  S + O2              SO2

They react with water to form acids. CO2 + H2O          H2CO3

With alkali to form salt and water only. CO2 + 2NaOH              Na2CO3 + H2O.

Nitrogen (iv) oxide form two salts with sodium hydroxide, since it is a mixed anhydride

2NO2 + 2NaOH               NaNO3 + NaNO2 + H2O

2.       BASIC OXIDES: These are oxides formed between a metal and oxygen. Na + O2          Na2O

They react with acids to form salt and water only. Na2O + 2HCl                 NaCl  + H2O.

3.       AMPHOTERIC OXIDES: These are oxides of metal which can behaves both has basic oxides and as acidic oxides. i.e. they can react with both acids and alkalis to form salt and water only.

Amphoteric oxides includes the oxides of aluminium (Al2O3), zinc (ZnO), lead(PbO), tin(SnO2)  BeO.

4.       NEUTRAL OXIDES: These are oxides which show neither acidic nor basic properties. Hence, they are neutral to litmus. e.g. CO, N2O, H2O, NO.

5.       HIGHER OXIDES: These are oxides containing a higher proportion of oxygen than the ordinary oxides. These higher oxides are classified into three groups namely the peroxides, dioxides and mixed oxides.

OZONE

Ozone is an unstable triatomic molecule of oxygen. In 1866, J, Soret , demonstrated that ozone was an allotropes of oxygen. Ozone is formed from atmospheric oxygen by lighting flashes. Small fraction of ozone was found in electrical machinery when they are in operation. Ozone exist in a layer at a height of about 25km above earth surface.

PHYSICAL PROPERTIES OF OZONE

1.       Ozone is a pale blue gas at ordinary temperature and pressure.

2.       It has a characteristic smell like that of dilute chlorine.

3.       It is poisonous at concentration above 100 parts per million.

4.       Pure ozone can be obtained as blue liquid by cooling ozonized oxygen to -112oC.

5.       Ozone is slightly soluble in water but it dissolves in turpentine.

CHEMICAL PROPERTIES OF OZONE

1.       Ozone is more reactive than oxygen. It decomposes into ordinary oxygen on heating. 2O3             3O2.

2.       Ozone is a more powerful oxidizing agent than oxygen. SO2 + O3                 SO3 + O2.

3.       Ozone liberates iodine from potassium iodide in acid solution

KI +H2SO4 +O2          I2 + O2 +K2SO4 + H2O.

TEST FOR OXYGEN

A glowing (wooden) splint is dipped into a test-tube of the gas (wooden) splint rekindles or relights.

USES OF OXYGEN

1.       Oxygen is used as an aid to breathing where the naturally supply of oxygen is insufficient.

2.       It is used in resuscitating fainting patient, aiding breathing in some lung diseases.

3.       Is used in oxy-ethyne and oxy-hydrogen flame for cutting and welding metals.

4.       Liquid oxygen and fuels are used as propellants for space rockets.

5.       Used in steel industry for the removal of carbon, sulphur and phosphorous.

6.       Used in the manufacture of chemical compound like H2SO4, HNO3, and CH3COOH.

 

 

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