COMPOUND OF OXYGEN
COMPOUND OF OXYGEN
OXIDES
Oxides are binary
compounds formed when elements combines with oxygen. Binary compounds are
compounds containing two elements only.
CLASSIFICATION OF
OXIDES
1.
ACIDIC OXIDES: These are oxides formed between a
non-metal and oxygen e.g.
C + O2 CO2; S
+ O2 SO2
They react with
water to form acids. CO2 + H2O
H2CO3
With alkali to form
salt and water only. CO2 + 2NaOH
Na2CO3 + H2O.
Nitrogen (iv) oxide
form two salts with sodium hydroxide, since it is a mixed anhydride
2NO2 + 2NaOH NaNO3 + NaNO2 + H2O
2.
BASIC OXIDES: These are oxides formed between a
metal and oxygen. Na + O2
Na2O
They react with
acids to form salt and water only. Na2O + 2HCl NaCl + H2O.
3.
AMPHOTERIC OXIDES: These are oxides of metal
which can behaves both has basic oxides and as acidic oxides. i.e. they can
react with both acids and alkalis to form salt and water only.
Amphoteric oxides
includes the oxides of aluminium (Al2O3), zinc (ZnO), lead(PbO), tin(SnO2) BeO.
4.
NEUTRAL OXIDES: These are oxides which show
neither acidic nor basic properties. Hence, they are neutral to litmus. e.g.
CO, N2O, H2O, NO.
5.
HIGHER OXIDES: These are oxides containing a
higher proportion of oxygen than the ordinary oxides. These higher oxides are
classified into three groups namely the peroxides, dioxides and mixed oxides.
OZONE
Ozone is an
unstable triatomic molecule of oxygen. In 1866, J, Soret , demonstrated that
ozone was an allotropes of oxygen. Ozone is formed from atmospheric oxygen by
lighting flashes. Small fraction of ozone was found in electrical machinery
when they are in operation. Ozone exist in a layer at a height of about 25km
above earth surface.
PHYSICAL PROPERTIES
OF OZONE
1.
Ozone is a pale blue gas at ordinary temperature
and pressure.
2.
It has a characteristic smell like that of dilute
chlorine.
3.
It is poisonous at concentration above 100 parts
per million.
4.
Pure ozone can be obtained as blue liquid by
cooling ozonized oxygen to -112oC.
5.
Ozone is slightly soluble in water but it
dissolves in turpentine.
CHEMICAL PROPERTIES
OF OZONE
1.
Ozone is more reactive than oxygen. It decomposes
into ordinary oxygen on heating. 2O3 3O2.
2.
Ozone is a more powerful oxidizing agent than
oxygen. SO2 + O3
SO3 + O2.
3.
Ozone liberates iodine from potassium iodide in
acid solution
KI +H2SO4 +O2 I2 + O2 +K2SO4 + H2O.
TEST FOR OXYGEN
A glowing (wooden)
splint is dipped into a test-tube of the gas (wooden) splint rekindles or
relights.
USES OF OXYGEN
1.
Oxygen is used as an aid to breathing where the
naturally supply of oxygen is insufficient.
2.
It is used in resuscitating fainting patient,
aiding breathing in some lung diseases.
3.
Is used in oxy-ethyne and oxy-hydrogen flame for
cutting and welding metals.
4.
Liquid oxygen and fuels are used as propellants
for space rockets.
5.
Used in steel industry for the removal of carbon,
sulphur and phosphorous.
6.
Used in the manufacture of chemical compound like
H2SO4, HNO3, and CH3COOH.
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