CHANGE OF STATES
CHANGE OF STATE
Evaporation:
Evaporation is the process where a liquid turns
automatically into vapour below its boiling point. Evaporation takes place at
all temperatures.
Factors That
Affect Evaporation:
The ate of evaporation is affected by the
following factors:
I. Nature of e liquid: High volatile liquids have high rate of evaporation
while liquids that have low volatility have low rate of evaporation.
II. Temperature of the surrounding: Rate of Evaporation will be high if the temperature of
the surrounding is high. Rate of evaporation will be low if temperature of the
surrounding is low.
III. Surface area of the liquid that is exposed:
The rate of evaporation of a liquid depends
on the area of the liquid surface that is exposed. The rate of evaporation will
be increase if the area of the liquid surface that is exposed is increased. It
will decrease if the area of the liquid surface that is reduced.
IV. Amount of pressure on the surface of the liquid:
The amount of pressure on the liquid surface
determine the rate of evaporation. The rate of evaporation will reduced if the
amount of pressure on the liquid surface is increased. It will increase if the
amount of pressure on the liquid surface is reduced.
V. Humidity: The
rate of evaporation will reduced if the relative humidity of the environment is
high. It will increase if the relative humidity of the environment is low.
VI. The presence of wind: The presence of wind gives room for evaporation by
getting rid of saturated air and allow room for more liquid to evaporate.
VII. Dryness of air: The rate of evaporation will increase if the air is very dry. It will
decrease if he air is moist.
Molecular
Explanation Of Evaporation:
According to kinetic theory of matter,
liquid as a matter is made of molecules. The molecules are in state of constant
random motion with certain amount of velocity and possess kinetic energy. When
the temperature of the molecules is increased, the kinetic energy of the
molecules is increase. This enable the molecules at the surface of the liquid
to brake away from the intermolecular force of attraction from molecules below
and exist as vapour. The presence of wind sweep the vapour away and create room
for more vapour.
Cooling
Effect of Evaporation:
When ever methylated spirit or petrol is
spilled any part of the body, The most important effect of evaporation is
cooling the body. When the body perspire during exercises, evaporation of the
sweat cools the temperature of the body.
Explanation Of Cooling Effect Of Evaporation
Using Kinetic Molecular Theory:
The sweat or the methylated spirit acquired its
latent heat of vaporization from the body and change to vapour or vaporized.
This acquisition of latent heat of vaporization by the sweat, from the body,
reduces the temperature of the body which causes cooling of the body.
Working
Principle of Refrigerator:
The working principle of a refrigerator is
based on the cooling effect of evaporation.
Explanation of Working Principle of
Refrigerator:
A volatile liquid called refrigerant or
liquefied gas is used. The refrigerant is contained in a copper pipes which
surround the freezing chamber of the refrigerator. As the refrigerant
evaporates, it absorbs latent heat of vaporization from the surrounding and
therefore cool the inside of the refrigerator and its contents. A compressor at
the back of the refrigerator removes the vapour, compresses it and pumps it
into condenser fixed with metal cooling fins that are attached at the back of
the refrigerator. The compressed vapour condenses and give out the latent heat
it absorbed initially, to the surrounding by convection and radiation. The
condensed vapour goes back into the freezing chamber and the process repeats
itself again and again.
BOILING
Boiling is the change of state of a
substance from liquid to vapour when its surrounding vapour pressure is equal
to the atmospheric pressure. Boiling can also be defined as the vaporization of
liquid molecules throughout the entire liquid. The temperature at which the
liquid boils to change to vapour is called saturated temperature. The
temperature at which the liquid boils is called boiling point.
Factors That Affect Boiling: The following factors affect boiling of a substance:
I. Impurities: The presence of impurities in a substance ( liquid ) increases the
boiling point of the liquid. A pure liquid boils at its exert boiling point.
II. Pressure: Increase in pressure increases the boiling point of a liquid while a
decrease in pressure reduces the boiling point of a liquid. Decrease in
pressure is the basics behind water boiling at a temperature below its boiling
point at the top of a mountain.
III. Mass of
the liquid: IV. Nature of the
liquid:
Similarities
Between Boiling And Evaporation:
Boiling.
Evaporation
• Does not
cause cooling.
It causes cooling
• It occurs in
every part of the liquid. It occurs at the
surface.
• It is affected
by the mass of e liquid. It is not affected by mass
of the .
Liquid
• It depend on
the nature of the
it does not depends on nature of
container because it absorbs its
Container
own
heat.
• It occurs at
a specific temperature. It occurs at all
temperature.
• Wind do not
assist boiling.
Wind assist evaporation
• Temperature
remains constant.
Temperature is not remain constant
Similarities between boiling and evaporation:
1. Escape of molecules is involved in both
cases. 2. Both of them depend on the nature of the liquid.
3. They are both affected by pressure. 4. They are
both affected by impurities
5. Acquisition of energy is involved in
both case
Relative Humility
is the ratio of the mass of water vapour present in a certain volume of air to
the mass of water vapour required to separate the same volume of air at the
same temperature.
Relative humidity
=
Dew Point is the
temperature at which the water vapour present in the air is just sufficient to
saturate it. Dew point is dependent upon prevalent atmospheric conditions like
temperature, wind and the amount of water vapour in the atmosphere.
When moist air
near the surface of the land cools until it reaches dew point, water vapour
originally present in the air begins to condense around tiny suspended dust
particles in the air. They form suspended water droplets in the atmosphere. A
collection of these suspended water droplets constitute a mist. In severe mist
situation, we have a fog.
A thick mist when formed high up in the atmosphere is known as a cloud. Instability in the condition of the cloud may cause rain to fall.
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